Just like phones, a modem's firmware is programmed to always search out the best possible signal based on the received RSRP and RSRQ signals. Unless it's a buggy firmware, there's really no need to lock it to any particular band. Due to environmental and tower changes in the signal, it's actually best to leave it on default automatic band selection.
If you ready need to, you can lock it to a specific band using AT commands such as
AT+QCFG="band",2e0,20000000000000000,0 - to lock it to band 66
You will need to consult the Quectel's "EC25 AT Commands Manual" (available on their website) to learn how to calculate the proper band parameters to send to the modem.
Try not to play around with random numbers, because your can really lock the signal out completely, then you'll have to factory reset the modem to get back to normal again. I would recommend finding the best LTE signal spot in your home, and just leaving the router there to let it do its thing.
